Adhesive chemistries — what to use where
Three families dominate: free-radical acrylate, cationic epoxide, and hybrid. Choice is driven by substrate energy, cure system (Hg vs LED), oxygen inhibition tolerance and downstream converting (overprint varnish, lamination).
Free-radical acrylate (e.g. INX AF-2110, Sun SunCure UFCA): fast cure, high gloss, best on coated paper and SBS board. Sensitive to oxygen inhibition on thin coats — needs 150–200 mJ/cm² UV-Hg or nitrogen inertion for UV-LED. Overprint with UV varnish only; solvent inks may lift the metallising.
Cationic epoxide (e.g. Actega Colorpoint EB): dark-cure continues after lamp exit, giving better bond on low-surface-energy films (BOPP, PET, PP). Runs at 80–150 mJ/cm², tolerates UV-LED without nitrogen. Cure completion in 24 h; can be overprinted with solvent or water-based inks after that window.
Hybrid (radical + cationic): compromise; used when the same press must switch between paper and film without changing adhesive.